KEGG   REACTION: R02132
Entry
R02132                      Reaction                               
Name
thiamin:oxygen 5-oxidoreductase
Definition
Thiamine + 2 Oxygen + H2O <=> Thiamine acetic acid + 2 Hydrogen peroxide
Equation
C00378 + 2 C00007 + C00001 <=> C02892 + 2 C00027
Comment
two-step reaction (see R00033+R00072)
Reaction class
RC00651  C00378_C02892
RC02755  C00007_C00027
Enzyme
1.1.3.23
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.3  With oxygen as acceptor
    1.1.3.23
     R02132  Thiamine + 2 Oxygen + H2O <=> Thiamine acetic acid + 2 Hydrogen peroxide
Reference
1  [PMID:2988447]
  Authors
Gomez-Moreno C, Edmondson DE.
  Title
Evidence for an aldehyde intermediate in the catalytic mechanism of thiamine oxidase.
  Journal
Arch Biochem Biophys 239:46-52 (1985)
DOI:10.1016/0003-9861(85)90810-0
Other DBs
RHEA: 21283

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Ontology (1)   
   KEGG BRITE (1)   
Chemical substance (5)   
   KEGG COMPOUND (5)   
Chemical reaction (3)   
   KEGG ENZYME (1)   
   KEGG RCLASS (2)   
All databases (9)   

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